Additive Manufacturing of Inorganic Transparent Materials for Advanced Optics
Navy STTR 2019.B - Topic N19B-T028
NAVAIR - Ms. Donna Attick - donna.attick@navy.mil
Opens: May 31, 2019 - Closes: July 1, 2019 (8:00 PM ET)

N19B-T028

TITLE: Additive Manufacturing of Inorganic Transparent Materials for Advanced Optics

 

TECHNOLOGY AREA(S): Materials/Processes ACQUISITION PROGRAM: PMA275 V-22 Osprey

OBJECTIVE: Develop an Additive Manufacturing (AM) process for depositing inorganic glasses with sufficient quality and precision for free form and gradient index optics.

 

DESCRIPTION: Naval Air Operations have a broad array of weapon and surveillance systems that utilize high performance optics. Many of these applications require greater wavelength transmission range, hardness, and temperature stability compared to polymers. The potential for utilizing AM technology to print glass lenses will provide the Navy the ability to (1) deposit net shape or near net-shape free-form optics, (2) locally adjust the index of refraction and other optical properties such as dispersion, (3) create high precision low thermal expansion meteorological frames that can form the basis for refractive optics, and (4) repair existing optical systems.

 

The benefits of AM are widely realized for structural systems; however, work on printing optical systems is still in its comparative nascency. The majority of the work has been primarily focused on polymers. Processes that have been demonstrated for printing optically transparent polymers include ink-jet printing [Ref 1] with/without in-situ ultraviolet (UV) curing [Ref 2] and multiphoton stereolithography (SLA) to directly polymerize resin [Refs 3-4].


These techniques have been used for rapid prototyping of non-imaging optics using Poly(Methyl Methacrylate) (PMMA) like plastics [Ref 4]. They have also been used to create curved display surfaces, sensors, display devices, and interactive devices [Refs 1-2], and to print 3D Gradient Index (GRIN) devices by locally adjusting the index of refraction during the layer-by-layer fabrication [Ref 3]. This work has progressed to the point that it is beginning to be commercialized and while it is currently suitable for non-imaging purposes the technology is approaching viability for ophthalmic applications.

 

Despite the benefits of inorganic glasses, there has been limited work applying AM processes to glasses. The high viscosity of glass when molten makes powder bed processes challenging because the bubbles fail to coalesce and escape due to buoyancy [Ref 5]. This can be overcome by using nanopowders to print a green part, followed by a slow high temperature burn-out/densification process [Refs 6-7]. Alternatively, fully dense material can be smoothly melted and deposited [Refs 8-9]. Both approaches have challenges and require significant development before optical devices can be successfully created. Currently no commercial AM system can be used to fabricate imaging quality optical glass with sufficient dimensional accuracy and surface finish.

 

A robust AM process to fabricate optical materials with good optical properties and surface quality is needed. This AM process should be able to deposit optical materials within the desired transmission band and provide a smooth optical surface quality so that minimum post-processing is needed. This process will allow engineering of new optical systems with volumetrically varying properties such as the index of refraction (i.e., GRIN lenses). Even with homogeneous glasses, AM has the potential to rapidly realize free form optics or to repair existing systems with no or minimal post (such as least amount of time for a final polish to achieve a desired surface flatness, such as lambda

/ 4) processing. This will dramatically enhance the logistics and maintenance of Navy aircraft and other systems.

 

To demonstrate a robust AM process, proposers are asked to develop an achromatic lens with a transmission window from 0.65 micrometer to 1.3 micrometer.

   Clear aperture must be 3 inches in diameter

  Effective Focal Length (EFL) must be 10 cm

   Resolution must be 100 lp/mm

   Athermalized design must work from -54 to 90 degrees Celsius

  No adhesive should be used to combine the doublets

 

Diameter Tolerance +0.00/-0.10 mm Focal Length Tolerance ±1% Surface Quality 40-20 Scratch-Dig Spherical Surface Power lambda /2

Spherical Surface Irregularity (Peak to Valley) lambda / 4 Centration =3 arcmin

Clear Aperture >90% of Diameter

Damage Threshold Pulse 5 J/cm2 (810 nm, 10 ns pulse, 10 Hz, 0.155 mm) CW 1000 W/cm (1070 nm, Ø0.971 mm)

 

In addition, provide the following analysis and measured data:

   Analyze Ray fan plots and spot diagrams

  Demonstrate that the optical path length is equal to sigma n delta s for the two discontinuity between the doublets

  Show the flatness of the wavefronts coming from a point source at the focus

  Show what does n (lambda) curve looks like

  Determine if power density at any image location is proportional to strength of corresponding object point?

  Determine the birefringence of the material delta n

  Determine the diffraction blur diameter

  Determine the aberrations for the lens using the spot diagram to show these effects

   Analyze spherical aberration; coma; astigmatism; distortion; transverse chromatic aberration

  Determine the wavefront errors for Seidel aberration

  Determine the Modulation Transfer Function (MTF) for this lens

  Show what the optical plot of the optical transmission looks like


PHASE I: Develop and demonstrate the feasibility of an AM process capable of the required optical properties, full densification, and smooth surface finish as provided in the description. The AM process should be able to realize a prescribed aspherical geometry with minimal post processing. Demonstration should include a fabrication plan of a representative achromatic lens with the specification provided in the description. Develop prototype plans to be developed under Phase II.

 

PHASE II: Fully develop the AM process, demonstrated in Phase I, that can be applicable to an array of naval optical component geometries. Include, in the prototype demonstration, the effectiveness of fabricating fully densified optical components with precision control of the part geometry, and smooth surface quality. Fully characterize the resulting geometry, and mechanical and microstructural properties achieved through the process to validate the effectiveness of the AM process.

 

PHASE III DUAL USE APPLICATIONS: Perform many experimental trials to define this additive manufacturing process since the development of an AM process for optical components is not a mature technology. Use simulation as a guide to help steer the direction of the experimentation; and to ensure the final product will meet the requirements of this topic as outlined in the specifications. Evaluate, by conventional metrology, the innovative achromatic doublet to ensure the AM process is on par with an achromatic produced by common practice. Transfer this process to platforms that have optical components.

 

Perform testing and make improvements to the AM Process based upon the results. Begin producing optical components for testing and use in military systems.

 

Laser manufacturers, camera manufacturers, and imaging technology manufacturers will benefit from this technology because they can now specify custom size optical components with unique transmission profiles that are not currently available with conventional optical processing.

 

REFERENCES:

1.   Willis, K., Brockmeyer, E., Hudson, S., and Poupyrev, I. “Printed Optics: 3D Printing of Embedded Optical Elements for Interactive Devices.” 25th Annual ACM Symposium on User Interface Software and Technology, Cambridge, MA, Oct. 7-10, 2012, pp. 589–598. https://dl.acm.org/citation.cfm?doid=2380116.2380190

 

2.   Brockmeyer, E., Poupyrev, I., and Hudson, S. “PAPILLON: Designing Curved Display Surfaces With Printed Optics.” 26th Annual ACM Symposium on User Interface Software and Technology, St. Andrews, Scotland, UK, Oct. 8–11, 2013, pp. 457–462. https://dl.acm.org/citation.cfm?id=2502027

 

3.   Urness, Adam C., Anderson, Ken, Ye, ChungfangWilson, William L., and McLeod, Robert R. "Arbitrary GRIN component fabrication in optically driven diffusive photopolymers." Opt. Express 23, 2015, pp. 264-273. https://doi.org/10.1364/OE.23.000264

 

4.   Wang, B., Zhang, Q., Liu, Z., and Gu, M. "Two-photon direct laser writing of ultra-compact micro-lens system for fiber-optical magnetic microscopy probe." 2017 European Conference on Lasers and Electro-Optics and European Quantum Electronics Conference, Optical Society of America, 2017.https://www.osapublishing.org/abstract.cfm?URI=CLEO_Europe-2017-CM_P_20

 

5.   Khmyrov, R., Grigoriev, S., Okunkova, A., and Gusarov, A. “On the Possibility of Selective Laser Melting of Quartz Glass.” Phys. Procedia, 2014, Volume 56, pp. 345–356. https://www.sciencedirect.com/science/article/pii/S1875389214002624

 

6.   Kotz, F., Arnold, K., Bauer, W., Schild, D., Keller, N., Sachsenheimer, K., Nargang, T.M., Richter, C. Helmer, D., and Rapp, B.E. “Three-dimensional printing of transparent fused silica glass.” Nature, 544, pp. 337-340 (20 April 2017). https://www.nature.com/articles/nature22061

 

7.   Nguyen, D.T., Meyers, C., Yee, T.D., Dudukovic, N.A., Destino, J.F., Zhu, C., Duoss, E.B., Baumann, T.F., Suratwala, T., Smay, J.E., and Dylla-Spears, R. “3D-Printed Transparent Glass.” Adv. Mater., 1701181, pp. 1-5, 28 April 2017.


8.   Luo, Junjie. "Additive manufacturing of glass using a filament fed process." Doctoral Dissertation, 2017. http://scholarsmine.mst.edu/doctoral_dissertations/2565/?utm_source=scholarsmine.mst.edu%2Fdoctoral_dissertatio ns%2F2565&utm_medium=PDF&utm_campaign=PDFCoverPages

 

9.   Klein, J., Stern, M., Franchin, G., Kayser, M., Inamura, C., Dave, S., Weaver, J. C., Houk, P., Colombo, P., Yang, M., and Oxman, N. “Additive Manufacturing of Optically Transparent Glass.” 3D Print. Addit. Manuf., 2(3), 2015, pp. 92-105. https://doi.org/10.1089/3dp.2015.0021

 

10.   Bogue, Robert. "Fifty years of the laser: its role in material processing." Assembly Automation, Volume 30, Number 4, 2010, pp. 317–322. https://www.emeraldinsight.com/doi/pdfplus/10.1108/01445151011075771

 

11.   Heinricha, Andreas, Ranka, Manuel, Maillarda, Philippe, Suckowa, Anne, Bauckhagea, Yannick, Rößlera, Patrick, Langa, Johannes, Shariffa, Fatin and Pekrula, Sven. "Additive manufacturing of optical components." Adv. Opt. Techn., 2016, pp 293-301. http://adsabs.harvard.edu/abs/2016AdOT..................................................... 5..293H

 

KEYWORDS: Optical AM; Optical additive manufacturing; Aberration; Lens; Achromat; 3D Graded Index lens; GRIN

 

TPOC-1:

Chandraika (John) Sugrim

Phone:

904-790-5916

 

TPOC-2:

Gregory Welsh

Phone:

301-342-3069

 

TPOC-3:

Kishan Goel

Phone:

301-342-0297

 

** TOPIC NOTICE **


NOTICE: The data above is for casual reference only. The official DoD/Navy topic description and BAA information is available on FedBizOpps at https://www.fbo.gov/index.php?s=opportunity&mode=form&id=82cbf6c93c77bee0ffa23d2cc8c2b422&tab=core&_cview=0

These Navy Topics are part of the overall DoD 2019.B STTR BAA. The DoD issued its 2019.B BAA STTR pre-release on May 2, 2019, which opens to receive proposals on May 31, 2019, and closes July 1, 2019 at 8:00 PM ET.

Between May 2, 2019 and May 30, 2019 you may communicate directly with the Topic Authors (TPOC) to ask technical questions about the topics. During these dates, their contact information is listed above. For reasons of competitive fairness, direct communication between proposers and topic authors is not allowed starting May 31, 2019
when DoD begins accepting proposals for this BAA.


Help: If you have general questions about DoD SBIR/STTR program, please contact the DoD SBIR/STTR Help Desk at 800-348-0787 or via email at sbirhelpdesk@u.group