Advanced AgO-Zn Battery with Wider Temperature Range and Improved Cycle Life
Navy SBIR FY2010.1


Sol No.: Navy SBIR FY2010.1
Topic No.: N101-054
Topic Title: Advanced AgO-Zn Battery with Wider Temperature Range and Improved Cycle Life
Proposal No.: N101-054-1516
Firm: Materials & Electrochemical Research (MER) Corp.
7960 S. Kolb Rd.
Tucson, Arizona 85756-9237
Contact: Raouf Loutfy
Phone: (520) 574-1980
Web Site: www.mercorp.com
Abstract: Silver-zinc rechargeable batteries are widely accepted as they offers 40% more runtime over lithium-ion batteries and 95% of their primary elements can be recycled and reused. However, these batteries need to achieve a further level of improvement with better cycle life and wider temperature range for large scale commercial acceptance. In this Navy SBIR program, Material and Electrochemical Research (MER) Corporation proposes a novel battery structure that differs from conventional battery design in that the electrodes are made out of a unique porous material that provides storage of silver and zinc containing liquids within their porous structure. These electrode structures do not need a impermeable separator. This new battery is simpler in construction, more efficient and less expensive than those that are currently available. The possibility that batteries having this type of electrode can be integrated with classic high temperature ionic salts for better cycle life and longevity will be explored. This Phase I work will include an assessment of the potential for manufacturability of these advanced large size format battery systems. Based on Phase I results, a 260V high capacity prototype will be developed in Phase II.
Benefits: The proposed electrodes are very innovative. When incorporated in AgO-Zn batteries they should improve the already large volumetric capacity. Application of this electrochemical system will significantly reduce the portability burden presently imposed by the limited electrical power storage capacity per unit weight of available electrochemical systems. Providing power for longer times can have an immediate impact on operations that requires navy use portable electronic devices. The proposed AgO-Zn power system that utilizes novel substrate materials could be useful when compact energy storage is needed. Examples are ocean exploration, offshore oil rig inspection, and I robotics.

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